The following example shows how to set a window icon in XAML.
<Window
xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
x:Class="SDKSample.MainWindow"
Icon="WPFIcon1.ico">
</Window>
The following example shows how to set a window icon in C# and WPF.
// Set an icon using code
Uri iconUri = new Uri("pack://application:,,,/WPFIcon2.ico", UriKind.RelativeOrAbsolute);
this.Icon = BitmapFrame.Create(iconUri);