Hi,
I have developed (in VS2010 - on a machine with Windows 7) a small solution 
which contains a WCF Service library and a Windows Service for hosting that WCF 
service. The App.config which is in my WCF service is:
<?xml version="1.0" encoding="utf-8" ?>
<configuration>
  <system.web>
    <compilation debug="true" />
  </system.web>
  <system.serviceModel>
    <behaviors>
      <serviceBehaviors>
        <behavior name="myWcfServiceBehavior">
          <dataContractSerializer maxItemsInObjectGraph="2147483647" />
          <serviceMetadata httpGetEnabled="false" />
          <serviceDebug includeExceptionDetailInFaults="true" />
          <serviceThrottling maxConcurrentCalls="2600" maxConcurrentSessions="2000" maxConcurrentInstances="3600" />
        </behavior>
      </serviceBehaviors>
    </behaviors>
    <bindings>
      <netTcpBinding>
        <binding name="mySecureNetTcpBinding"
                  closeTimeout="00:01:00" openTimeout="00:01:00" receiveTimeout="00:01:00" sendTimeout="00:01:00"
                  transferMode="Buffered"
                  maxBufferPoolSize="2147483647" maxBufferSize="2147483647" maxReceivedMessageSize="2147483647">
          <readerQuotas maxDepth="2147483647"
                        maxStringContentLength="2147483647"
                        maxArrayLength="2147483647"
                        maxBytesPerRead="2147483647"
                        maxNameTableCharCount="2147483647" />
          <security mode="None" />
        </binding>
      </netTcpBinding>
    </bindings>
    <services>
      <service name="WcfServiceLibrary1.Service1"
               behaviorConfiguration="myWcfServiceBehavior">
        <host>
          <baseAddresses>
            <add baseAddress="net.tcp://localhost:8001/Service1" />
          </baseAddresses>
        </host>
        <endpoint name="WcfServiceLibrary1.Service1"
                  address=""
                  binding="netTcpBinding"
                  bindingConfiguration="mySecureNetTcpBinding"
                  contract="WcfServiceLibrary1.IService1">
        </endpoint>
        <endpoint address="mex" binding="mexTcpBinding"
                  bindingConfiguration=""
                  contract="IMetadataExchange" />
      </service>
    </services>
  </system.serviceModel>
  <system.diagnostics>
    <sources>
      <source name="System.ServiceModel"
              switchValue="Error, Critical"
              propagateActivity="true">
        <listeners>
          <add name="traceListener"
              type="System.Diagnostics.XmlWriterTraceListener"
              initializeData="c:\log\WCF_Errors.svclog"  />
        </listeners>
      </source>
    </sources>
  </system.diagnostics>
</configuration>This file is also in my windows service with the same configurations.
My service code is something very simple:
File IService1.cs:
using System;
using System.Collections.Generic;
using System.Linq;
using System.Runtime.Serialization;
using System.ServiceModel;
using System.Text;
namespace WcfServiceLibrary1
{
    // NOTE: You can use the "Rename" command on the "Refactor" menu to change the interface name "IService1" in both code and config file together.
    [ServiceContract]
    public interface IService1
    {
        [OperationContract]
        string GetData(int value);
    }
} 
and file Service1.cs: 
using System; 
using System.Collections.Generic; 
using System.Linq;
using System.Runtime.Serialization; 
using System.ServiceModel;
using System.Text; 
namespace WcfServiceLibrary1
{
    // NOTE: You can use the "Rename" command on the "Refactor" menu to change the class name "Service1" in both code and config file together.
    public class Service1 : IService1
    {
        public string GetData(int value)
        {
            return string.Format("You entered: {0}", value);
        }
    }
}
I have hosted this wcf service in my windows service in this way:
using System;
using System.Collections.Generic;
using System.ComponentModel;
using System.Data;
using System.Diagnostics;
using System.Linq;
using System.ServiceProcess;
using System.Text;
using System.ServiceModel;
using WcfServiceLibrary1;
using System.IO;
namespace WindowsService1
{
    public partial class Service1 : ServiceBase
    {
        internal static ServiceHost myServiceHost = null; 
        public Service1()
        {
            InitializeComponent();
        }
        protected override void OnStart(string[] args)
        {
            StreamWriter sw;
            try
            {
                if (myServiceHost != null)
                    myServiceHost.Close();
                myServiceHost = new ServiceHost(typeof(Service1));
                myServiceHost.Open();
            }
            catch (Exception exc)
            { 
                sw = new StreamWriter(@"C:\Log\Err.Txt");
                sw.Write(exc.Message);
                sw.Close();
            }
        }
        protected override void OnStop()
        {
            StreamWriter sw;
            try
            {
                if (myServiceHost != null)
                {
                    myServiceHost.Close();
                    myServiceHost = null;
                }
            }
            catch (Exception exc)
            {
                sw = new StreamWriter(@"C:\Log\Err.Txt");
                sw.Write(exc.Message);
                sw.Close();
            }
        }
    }
}
I have added an Installer where I configured properties: Account: 
NetworkService for serviceProcessInstaller 
and StartType: Automatic for serviceInstaller.
I built the project, after that I install the windows service with 
InstallUtil. After that I looked in my log file if something is wrong. 
Unfortunately, I didn't find anything. Atfer that I enter in Computer Management 
(I have Windows 7 and VS2010) and I started my Windows Service. After that I 
looked again in my log file and in Logs  from Event Viewer (from Application), 
but again I didn't find anything.
Unfortunately, when I want to consume (to register) that address, I can't do 
this thing. I tried with Add Service refference and after that with SvcUtil but 
the result is the same. 
When I want to add service address  net.tcp://localhost:8001/Service1 with 
Add Service Refference it appears on the screen An error (Detail) occured while 
attempting to find services at 'net.tcp://localhost:8001/Service1'. 
I checked the metadata addressed, but it seems that it's OK. Maybe I'm wrong 
of course.
I run netstats -ap tcp and I didn't see my TCP protocol: 8001.
Please help me and tell me what it's wrong.
Sincerely Yours,
Florin G