check record already exists using combobox incsharp

Question

 Note: it is windows application.

Name combobox
Days combobox

in the name retrieved from the database and display into the combobox.
in the days column manually typed in the code sunday to saturday.

in the run mode i select the name and select the days and click the save button. the records are saved in the database. it is working fine.

for example as follows;

Name Suresh
Days Sunday

the above record is saved in the database.

then i have one search button,when i click the search button from the database records are displayed in the datagridview,when i click the datagridview, the particular record is displayed in the respective combobox.

suppose when i select the suresh and select the sunday and click save button, 
 
that time validate ,For suresh sunday is already exists.

for that how to validate the Combobox.using csharp.

how can i do using csharp

 Note: it is windows application.