How to Print the pdf and Excel formate from database

Question

UserId
Password
FName
LName
Address
Country	Select Country INDIA USA USSR UK
Contact
Email
Gender	Male Female
Education	BCA MCA M.Tech
	Print

pls tail me how to export the pdf and excel formate from database pls tail me how to write the code 
1=> fill all textbox than click the print button to generated the pdf and excel form 
pls suggest how to write the code