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Hi,
To start learning ASP.NET with C# check these links:
Learning ASP.NET: http://samples.gotdotnet.com/quickstart/aspplus/
Learning HTML: http://www.w3schools.com/html/
Learning C#: http://cplus.about.com/od/learnin2/
Book for Beginners: Microsoft Visual C# .NET Step by Step--Version 2003, by Jon Jagger, John Sharp http://www.amazon.com/exec/obidos/ASIN/0735619093/qid=1112246771/sr=2-1/ref=pd_ka_b_2_1/002-3160732-2764852
For more C# resources: http://msdn.microsoft.com/vcsharp/
Hope these helps. Wish you good luck with programming.
Cheers,
Yasser