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mahesh start method willbe called once or it will run like looping untill i dont stop sevice
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Here is an article that shows you how to build a Windows Service. Instead of writing to a text file, you will write your code to send email here.
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Mahesh can u give any link that provide information about how to build service process
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Yes Mahesh is right, you should use other options instead of using a web application. Your problem occurring might due to Application Pool recycling.
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If your code is sending emails for 1 hour but not for 4-5 hrs, it seems like a bug in the code. Also, I am not sure if it is a good idea to put your send email code in the Global.asax file. You should either build a service or a job process (separate exe and schedule it as a job) or create a job in SQL Server.
BTW Restarting server does not need you to restart IIS. IIS should automatically restart and so your application and so your Global.asax.